The incineration of household waste is part of the management of domestic waste. Can't the same be done with radioactive waste? Once a difficult long-lived element has been isolated, can't it be destroyed? To get rid of stubborn radioactive elements that live for hundreds of years or more, in principle all we have to do is change their nature, turn them into calmer, more stable nuclei.
Paradoxically, they may have to pass through states of being much more radioactive but more short-lived nuclei. To get rid of technetium-99, a fission product that lives for 210,000 years, we can transmute it to technetium-100 through the capture of a neutron. Technetium-100 then decays within a few minutes to a stable ruthenium nucleus. The radioactive decay process has been sped up (NB: in a reactor, this process uses a lot of neutrons).
The long-lived radioelements to be destroyed as a priority, because they are the most toxic, are heavy nuclei known as the minor actinides – neptunium, americium, curium – which make up around 0.2% of spent fuel. They are fragile nuclei. If they are bombarded by neutrons with the right amount of energy, they undergo fission, which destroys them.
Attempts will be made to destroy them by incorporating them into fuel for specialised reactors. Current reactors, which work with slow neutrons, are not very effective. But with fast neutrons, almost all the actinides become fissile, and therefore destructible. The shutdown in France in 1997 of the fast neutron reactor programme delayed the possibility of being able to burn these actinides. To reach that point again on an industrial scale will mean waiting for the arrival of the Generation IV reactors.
Destroying troublesome nuclei is an arduous task. With the incineration of household waste, you are tackling atoms and molecules. It's simple chemistry. Transforming nuclei one by one is much more difficult. You need a lot of neutrons, and there are a lot of nuclei to be transmuted!
The quantities that can be incinerated are limited. A 1 gigawatt reactor (3 GW power output) running 24 hours a day burning only actinides would destroy only 1.1 tonnes a year. This might seem disappointing at first glance, but reactors do not generate much of this waste (a PWR reactor generates 18 kg of minor actinides each year). Our incinerator reactor could in theory burn the actinides from 58 French reactors.
Rather than an alternative, incineration turns out to be more of a complement to disposal in deep repositories; it could never replace it. However, by reducing the volume and toxicity to be disposed of, incinerating the most troublesome waste would allow the specifications for long-term geological disposal facilities to be revised downwards. Transmutation is slated as the ultimate goal of research into waste.
Transmutation could not be used for high-activity waste already produced and conditioned.
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