Alongside the fission products found in the core of nuclear reactors there are elements known as actinides, heavy nuclei that also contribute to the radioactivity of the spent fuel. These 'transuranic' nuclei, heavier than uranium, are produced by neutron captures which do not lead to nuclear fission. Their name comes from the element actinium (Z=89), a heavy metal which narrowly precedes uranium in Mendeleev’s periodic table. By the way, uranium itself, which can be found in nature as well as artificially produced, belongs to this family.
Plutonium is by far the most commonly produced actinide, with plutonium 239 being its most abundant isotope. Nuclear reactors also generate other, 'minor' actinides in smaller quantities: such as neptunium 238, americium 241 and 243 as well as curium 244 and 245.
The quantities of minor actinides produced may look insignificant when compared with the amount of fission products or plutonium brought into existence. The spent fuel released by a large pressurised water reactor (with a power output of 1.3 gigawatts) every year contains on average: 33 tons of uranium enriched to 0.9%, 360 kg of plutonium, 1.2 tons of fission products and 27 kg of minor actinides. Statistics show that among these 27 kilograms there will be 14 kg of neptunium, 12 kg of americium and 1 kg of curium.
At the time when the fuel is retrieved from the reactor, the activity of plutonium and minor actinides is tiny by comparison with that of the fission products. In that case, why bother dealing with it at all? The first reason is that the actinides have much longer half-lives than most fission products, which poses a problem for the long-term storage of radioactive waste. The second reason is that heavy nuclei can also emit alpha radiation, which, if absorbed into the body, is more dangerous than the beta radiation emitted by fission products.
Nevertheless, this potential radiotoxicity is not a direct danger. Like arsenic, plutonium and minor actinides must enter our stomachs or our lungs in order to become damaging. Fortunately for us, these elements are both too heavy to remains in the air and are often found in the form of insoluble oxides which are not mobile.
After approximately 200 years, the activity and potential toxicity of minor actinides in radioactive waste will be greater than that of the fast-decaying (in comparison) fission products. This is why the clearing up of radioactive waste involves handling plutonium and minor actinides in order to leave a cleaner environment to future generations. With spent fuel reprocessing, plutonium that is separated can be burned in future fast reactors. Minor actinides are effectively neutralized for thousands of years by encasing them in glass or ceramic before burying them in deep underground.
It is possible to go one step further, and either to make actinides disappear by transmuting them into other elements. Another approach is to avoid to let them form in reactors. Thorium-based nuclear reactors have the advantage of no actinide nor plutonium production, a property which makes them appealing.
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